Reinvestigation of the reaction between
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Ryszard W Kinas; Andrzej Okruszek; Wojciech J Stec
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Article
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2002
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Elsevier Science
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French
โ 195 KB
Alkali metal salts of diethyl phosphites act as nucleophiles or electron donors in reactions with diethyl phosphorochloridate. Evidence is provided that formation of the direct P(IV) P(IV) bond proceeds via a single electron transfer process (SET) from phosphite anion to phosphorochloridate.