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Evidence for a bis(alkylidene)silacyclopropane intermediate in the platinum-mediated formation of a silacyclobutene

✍ Scribed by Dema, Anne C.; Lukehart, C. M.; McPhail, Andrew T.; McPhail, Donald R.


Book ID
126091819
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
607 KB
Volume
112
Category
Article
ISSN
0002-7863

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## Abstract In __m__‐nitrobenzaldoxime a strongly enhanced loss of OHβ‹… is observed as compared with the p‐nitro compound. Evidence is presented for a fragmentation mechanism involving the formation of a cyclohexadiene‐type intermediate ion formed by a rearrangement of the hydroxyl hydrogen to the p