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Evaluation of titanium alkoxides and aryloxides in the Kulinkovich cyclopropanation of carboxylic esters

✍ Scribed by Jae Chol Lee; Moo Je Sung; Jin Kun Cha

Book ID
104230220
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
65 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Systematic evaluation of several titanium alkoxides and aryloxides was undertaken in the titanium-mediated cyclopropanation reactions of carboxylic esters. Chlorotitanium triisopropoxide and/or methyltitanium triisopropoxide were found to be the reagents of choice for the olefin exchange modification, whereas the original Kulinkovich process proved to be insensitive to the nature of titanium alkoxides and aryloxides.

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