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ChemInform Abstract: Evaluation of Titanium Alkoxides and Aryloxides in the Kulinkovich Cyclopropanation of Carboxylic Esters.

✍ Scribed by Jae Chol Lee; Moo Je Sung; Jin Kun Cha


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
32
Category
Article
ISSN
0931-7597

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✍ Oleg G. Kulinkovich; Dzmitry G. Kananovich πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

## Abstract A procedure for the preparation of __cis__‐1,2‐dialkylcyclopropanols by titanium(IV) alkoxide‐mediated cyclopropanation of carboxylic esters with Grignard reagents, involving the addition of 1.5 equiv. of a higher homologue of ethylmagnesium halide to a mixture of 1 equiv. of carboxylic