Evaluation of the Force Constants of Bonds Involving Hydrogen Atoms
β Scribed by TORKINGTON, P.
- Book ID
- 109560596
- Publisher
- Nature Publishing Group
- Year
- 1949
- Tongue
- English
- Weight
- 103 KB
- Volume
- 164
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/164113a0
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π SIMILAR VOLUMES
The intermolecular stretching vibration of hydrogen bonded complexes between phenol derivatives and tetramethylthiourea or dimethylthioformamide is observed in the range 113 -131 cm-'. The corresponding force constants ko are computed using the Lippincott-Schroeder potential function and the matrix
Ab initio SCF h10 calculations (with the 4-31G basis set) have been carried out to determine the equilibrium Seometry, vibmtional frequencies, dipole-moment derivatives, and force constants for intermolecular modes of the formamide dimer and its d4 and d6 derivatives. The results are correlated with