Relationships between the lengths, orders, hybridization of the atoms, and force constants of carbon—nitrogen and carbon—oxygen bonds
✍ Scribed by E. M. Popov; G. A. Kogan; V. N. Zheltova
- Book ID
- 112363362
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 614 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-5760
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bulky groups. In the erythro series, on the other hand, chelation requires an increase in the proportion of (E,) or (Ec), and 5 2 3 progressively decreases to a limiting value which agrees closely with the calculated figure. Although both of these rotamers have four adjacent bulky groups, chelation
## Abstract A generalized relationship to describe bond coupling constants is introduced. This expression includes the contributions for hybrid orbitals and the net atomic charges. The resulting expression provides an excellent description of directly bonded CH coupling constants. This equation is