Evaluation of the dipole moments of organic ions in the gas phase
โ Scribed by O. Bortolini; L. Olimpieri; P. Traldi
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 293 KB
- Volume
- 29
- Category
- Article
- ISSN
- 1076-5174
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โฆ Synopsis
The dipole moments of a series of substituted benzene radical cations were evaluated on the basis of mass displacements from the expected instrumental value by ion trap experiments. Mass displacements represent a direct measure of the total polarizability, giving access to both the electronic and dipolar polarizabilities, depending on the characteristics of the analyte under investigation. A linear relationship was found between the dipolar polarizabilities and the dipole moments of the corresponding neutrals.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Mass-spectral and n.m.r. analysis of thiophenes labeled by exchange with deuteriosulfuric acid establishes that exchange at the 2 and 5 positions is essentially complete before any deuterium is incorporated at positions 3 and 4. Thus, such exchange is a satisfactory procedure for positionspecific la