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Evaluation of limiting-induced shifts of disubstituted adamantane derivatives on the basis of shift additivity

✍ Scribed by M. Hájek; L. Vodička; J. Hlavatý

Publisher: John Wiley and Sons
Year: 1975
Tongue: English
Weight: 273 KB
Volume: 7
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270071102

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✦ Synopsis

Abstract

A quantitative interpretation of ^1^H NMR spectra of symmetrically disubstituted adamantane derivatives (2,4‐adamantanedione, 2,6‐adamantanedione and 2,4‐adamantanetdiol) with shift reagents is reported. Assumptions are made of shift additivity and an average coordination of one molecule of the shift reagent to both functional groups. A much better fit between the experimental and the calculated set of limiting‐induced shifts was obtained for calculations based on shift additivity.

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