Evaluation of electron inelastic mean free paths for selected elements and compounds
β Scribed by Powell, C. J.; Jablonski, A.
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 96 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0142-2421
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β¦ Synopsis
We have performed an evaluation of calculated and measured electron inelastic mean free paths (IMFPs) for selected materials and for electron energies between 50 eV and 10 000 eV. This evaluation is based on IMFPs calculated from experimental optical data and on IMFPs measured by elastic-peak electron spectroscopy. The methods used for the calculations and measurements are briefly described, together with the various sources of uncertainty. We have evaluated calculated and measured IMFPs for four elements (Fe, Mo, W and Pt) and calculated IMFPs for six compounds (aluminum oxide, silicon dioxide, potassium chloride, poly(butene-1-sulfone), polyethylene and polystyrene). Good consistency was found among the calculated IMFPs and reasonable consistency was found between the calculated and measured IMFPs. The degree of consistency in each case is similar to that found in a previous evaluation of calculated and measured IMFPs for Al, Si, Ni, Cu, Ge, Ag and Au. Finally, we have compared IMFPs from the predictive IMFP equation TPP-2M with recommended IMFPs for Ni, Cu, Ag and Au obtained from the earlier evaluation. This comparison indicated that the standard uncertainty of IMFPs from the TPP-2M equation, relative to the recommended IMFPs, was 1.0 Γ or 9.2%.
π SIMILAR VOLUMES
Intensity ratios of electrons backscattered elastically from thick, amorphous Si, polycrystalline Ag and Au, as well as various (vacuum evaporated, electrodeposited layers and metallic sheets) polycrystalline Ni samples, were measured using high energy resolution and two different experimental geome
Gries has recently reported [ Surf. Interface Anal. 24, 38 (1996) ] an atomistic model for inelastic electron scattering relevant to Auger electron spectroscopy and x-ray photoelectron spectroscopy and has derived an equation (designated G1) for the estimation of inelastic mean free paths (IMFPs). W
Theoretical values of the inelastic mean free path (IMFP) and their electron-energy dependence are available in the literature from predictive formulae for various categories of materials, such as elemental solids, inorganic and organic compounds. in contrast, the experimental IMFP values were deter