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Evaluation of Chiral Oxazolines for the Highly Enantioselective Diethylzinc Addition to N -(Diphenylphosphinoyl) Imines †

✍ Scribed by Zhang, Xiao-Mei; Zhang, Hai-Le; Lin, Wen-Qing; Gong, Liu-Zhu; Mi, Ai-Qiao; Cui, Xin; Jiang, Yao-Zhong; Yu, Kai-Bei

Book ID
126475520
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
146 KB
Volume
68
Category
Article
ISSN
0022-3263

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The first use of chiral oxazoline ligand
The first use of chiral oxazoline ligands in the highly enantioselective diethylzinc addition to diphenylphosphinoyl imines
✍ Xiaomei Zhang; Wenqing Lin; Liuzhu Gong; Aiqiao Mi; Xin Cui; Yaozhong Jiang; Mic 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 62 KB

A series of chiral oxazolines, which had been conveniently prepared from commercially available (1S,2S)-2-amino-1phenylpropane-1,3-diol, was applied in the diethylzinc addition to diphenylphosphinoyl imines to give high yields of 68-84% and excellent e.e. values of 90-93%.