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Evaluation of acidity constants in dioxane—water mixtures by spectrophotometric and potentiometric pH titrations

✍ Scribed by A.Gustavo Gonzalez; F. Pablos

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 459 KB
Volume: 251
Category: Article
ISSN: 0003-2670
DOI: 10.1016/0003-2670(91)87153-x

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✦ Synopsis

Autoprotolysis

constants and correction factors for a glass electrode in lo-508 (v/v) dioxane-water mixtures were calculated by using a procedure based on the titration of a strong acid with a strong base in the studied media. The correction factors were obtained at each titration point and therefore they cover the whole pH scale. The use of these parameters for evaluating acidity constants in dioxane-water mixtures by potentiometric and spectrophotometric methods is discussed.

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