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Etudes sur les composés organométalliques XIV. Réactivité du tétrabenzyltitane (lère communication)

✍ Scribed by Jacques Causse; Raffaele Tabacchi; André Jacot-Guillarmod

Publisher
John Wiley and Sons
Year
1972
Tongue
German
Weight
403 KB
Volume
55
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The reactivity of tetrabenzyltitanium with acetone, benzophenone, butanal, acetyl chloride, butyl acetate, ethyl chloroformate, benzonitrile, propylene oxide, carbon dioxide has been investigated.

The results show that tetrabenzyltitanium reacts like benzylmagnesium‐chloride. The socalled ‘anomalous reaction’ is observed. Benzonitrile, propylene oxide and carbon dioxide, on the other hand, do not react.

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