## Studies of Organometallic Compounds XVIII: Synthesis and Caracterisation of p-0x0-bis(dicyclopentadienylmethyltitanium IV) ## Summary ( C P ~T ~C H , ) ~O is obtained by reacting (Cp2TiC1),0 with methyllithium. IR., NMR. and MS. spectrum are reported. Autocatalytic decomposition of the produ
Etudes sur les composés organométalliques. XIX. Synthèse et caractérisation de composés alkoxy (alkyl)titane (IV)
✍ Scribed by Edouard Marc Meyer; André Jacot-Guillarmod
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- German
- Weight
- 238 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Studies of Organometallic Compounds. Synthesis and Characterization of Some Alkoxy (alkyl)‐titanium(IV) Compounds
Alkoxy(benzyl)titanium and alkoxy(cyclohexyl)titanium compounds are prepared by alcoholysis of tetrabenzyl‐ and tetracyclohexyltitanium. Structural features are investigated by means of ^1^H‐NMR.
📜 SIMILAR VOLUMES
**Studies of Organometallic Compounds. XVII Synthesis of Tetracyclohexyltitanium** Tetracyclohexyltitanium is prepared by reaction of TiCl~4~ or Ti(OC~4~H~9~)~4~ with dicyclohexylmagnesium in pentane or ether at ‐ 30°. Some aspects of its reactivity and its decomposition are described.
## 1 XI67) Summary. The complexcs between different diorganotin cations and substituted 1,lO-phenanthrolines in aqueous solution containing acctatc ion have been investigated. Diorganotin cations can co-ordinate two acetate ions. One of thcsc niay be replaced by a 1.10-phenanthroline derivative. A
## Abstract **Studies of Organometallic Compounds, XX. Selectivity of 1,4‐Addition of Benzyltitanium Compounds with Benzylildenacetone** Tetrabenzyltitanium and dialkoxydibenzyltitanium compounds give essentially 1,4‐ addition with __trans__‐4‐phenyl‐3‐buten‐2‐one.