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Etudes sur les composés organométalliques. X [1]. Action d'organomagnésiens sur la benzophénone

✍ Scribed by George Jon Dubsky; André Jacot-Guillarmod

Publisher
John Wiley and Sons
Year
1970
Tongue
German
Weight
400 KB
Volume
53
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Various Grignard reagents and their diorganomagnesium complexes with ether or pyridine have been reacted with benzophenone, using different mole ratios and orders of addition. Analysis of the reaction products has provided information as to probable reaction mechanisms of addition and reduction. A monomeric diorganomagnesium reagent, favoured either by addition of the reagent to the ketone or by complexation of the reagent with pyridine, enhances if possible the reduction reaction.

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