Etude théorique et possibilités d'application de la méthode de «variations continues» [1] aux complexes très dissociés
✍ Scribed by M. Marcantonatos; R. Buffle; D. Monnier
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- German
- Weight
- 293 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
4 theoretical study of the possibilities of applicability to very unstable complexes of the ([continuous variation)) principle shows that the general equation of a theoretical Job's curve can be reduced, for limiting values of x and 1 -x (x being the ligand's mole fraction), to expressions permitting the determination of the number t m ) ) of the central groupes, the number cnn of the ligands, and the stability constants of highly dissociated complexes. Theoretical and practical limitations are discussed.
2)
L'abrhiation VC. est utilisie dans le present travail. Fraction molaire du ligand (v. note4)).
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