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Etude de la regio et de la stéréospecificité de l'addition du phénylnitriloxyde au 3-methyl-2-benzylidene indan-1-one. Structure de l'adduit obtenu

✍ Scribed by Toupet, L. ;Chekti, R. ;Soufiaoui, M. ;Carrie, R.


Book ID
114509900
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
291 KB
Volume
49
Category
Article
ISSN
0108-2701

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Etude de l'addition nucleophile de quelq
✍ Odile Ruel; Eric Guittet; Sylvestre Julia 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 200 KB

The >/ 92 % regioselective nucleophilic trans-addition of 2-methyl-2-propanethiol to primary, secondary ond tertiary 1-alkyn-3-ols, catalyzed by 0,l equiv. of potassium hydroxide powder, affords good yields of anti-Markovnikoff products. Pour confirmer la structure du compose (2, R1=R2=CH3,