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Ethynylogization of a Coarctate Fragmentation

✍ Scribed by Rainer Herges; Daniel Geuenich; Götz Bucher; Christina Tönshoff

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
110 KB
Volume
6
Category
Article
ISSN
0947-6539

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✦ Synopsis

Coarctate reactions form a separate class of elementary closed-shell processes in addition to polar and pericyclic reactions. Hence, they also follow a different homology principle. Whereas vinylogous polar and pericyclic reactions differ in the length of the reacting system by a double bond, coarctate reactions can be homologized (ethynylogized) by extending a known system by a triple bond. The prediction, which is based on theoretical considerations, is confirmed experimentally by the fragmentation of cyclopropylethynyl nitrene to cyano acetylene and ethylene, a reaction that is ªethynyloguousº to the known fragmentation of cyclopropyl nitrene to ethylene and HCN.

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