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Ethylene/Norbornene Copolymerization Behavior of Bis(phenoxy−imine)Ti Complexes Combined with MAO

✍ Scribed by Terao, Hiroshi; Iwashita, Akihiko; Ishii, Seiichi; Tanaka, Hidetsugu; Yoshida, Yasunori; Mitani, Makoto; Fujita, Terunori

Book ID: 126800072
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 916 KB
Volume: 42
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma900890b

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This contribution reports ethylene and propylene polymerization behavior of a series of Ti complexes bearing a pair of phenoxy-imine chelate ligands. The bis(phenoxy-imine)Ti complexes in conjunction with methylalumoxane (MAO) can be active catalysts for the polymerization of ethylene. Unexpectedly,