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Fluorinated Bis(phenoxy—imine) Ti Complexes with MAO: Remarkable Catalysts for Living Ethylene and Syndioselective Living Propylene Polymerization

✍ Scribed by Rieko Furuyama; Junji Saito; Seiichi Ishii; Haruyuki Makio; Makoto Mitani; Hidetsugu Tanaka; Terunori Fujita

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Propylene Polymerization Behavior of Flu
Propylene Polymerization Behavior of Fluorinated Bis(phenoxy-imine) Ti Complexes with an MgCl2-Based Compound (MgCl2-Supported Ti-Based Catalysts)
✍ Yasushi Nakayama; Junji Saito; Hideki Bando; Terunori Fujita 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

## Abstract Summary: Fluorinated bis(phenoxy‐imine)Ti complexes 1–3 combined with MgCl~2~/__i__‐Bu~__n__~Al(OR)~3−__n__~ (MgCl~2~‐supported catalysts) were able to polymerize propylene in a living fashion at room temperature to provide slightly to highly syndiotactic poly(propylenes) (PPs) with ext