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Ethylene oligomerization using iron complexes: beyond the discovery of bis(imino)pyridine ligands

✍ Scribed by Boudier, Adrien; Breuil, Pierre-Alain R.; Magna, Lionel; Olivier-Bourbigou, Hélène; Braunstein, Pierre


Book ID
121399089
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
720 KB
Volume
50
Category
Article
ISSN
1359-7345

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Several bis(imino)pyridine cobalt (II) complexes have been synthesized and used in ethylene oligomerization in 1-methyl-3-butylimidazolium tetrachloroaluminate (BMI•AlCl 4 ) ionic liquid activated by methylaluminoxane (MAO). The ligand substitution pattern, with halogen, methyl or trifluoromethyl un