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Ethylene and Phenylacetyl Chloride in the Friedel-Crafts Reaction. Novel Syntheses of 2-Tetralones and Benzofuranones 1

โœ Scribed by BURCKHALTER, J. H.; CAMPBELL, J. ROBERT


Book ID
120592784
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
519 KB
Volume
26
Category
Article
ISSN
0022-3263

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A simple one-pot stereoselective transformation of tert-butyl 3-aryl-3-hydroxy-2-methylenepropanoates, the Baylis-Hillman adducts obtained from t-butyl acrylate, into (E)-2-arylideneindan-1-ones involving one inter-and one intramolecular Friedel-Crafts reaction is described.