Ethyl phenylsulfonylacetate
✍ Scribed by Ding, Jin-Chang ;Su, Wei-Ke ;Wu, Hua-Yue ;Liu, Miao-Chang ;Ng, Seik Weng
- Book ID
- 104481474
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 136 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.038 wR factor = 0.098 Data-to-parameter ratio = 12.7
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📜 SIMILAR VOLUMES
The structure of the title compound, C 13 H 16 O 3 S, prepared by the reaction of the lithium enolate of cyclopentanone with phenylvinyl sulfoxide and subsequent oxidation with m-chloroperoxybenzoic acid (m-CPBA), shows the phenylsulfonylethyl side chain to be bonded to the cyclopentanone ring in a
In the title compound, C 21 H 17 NO 4 S, all bond lengths and angles show normal values. The sulfonyl-bound phenyl ring forms a dihedral angle of 88.31 (1) with the mean plane of the carbazole fragment. The crystal packing is stabilized by weak intermolecular -, C-HÁ Á Á and C-HÁ Á ÁO interactions.
In the title compound, C 16 H 14 N 2 O 4 S, the phenyl and quinoxaline 1,4-dioxide planes are approximately perpendicular, with a dihedral angle of 85.8 (2) .
In the title molecule, C 35 H 27 NO 3 S 2 , the indole system is approximately planar. The phenyl rings of the phenylsulfonyl and phenylsulfanyl groups are oriented at angles of 74.69 (7) and 88.35 (9) , respectively, to the indole ring system. The dihedral angle between the two phenyl rings of the