The non-H atoms of the title molecule, C 12 H 11 NO 3 , are nearly coplanar, with an r.m.s deviation of 0.054 A ˚. There are two intramolecular C-HÁ Á ÁO hydrogen bonds. Pairs of the molecules are linked into centrosymmetric dimers via intermolecular C-HÁ Á Á interactions. The dimers are stacked alo
Ethyl 7-hydroxy-1H-indole-1-carboxylate
✍ Scribed by Senthil Kumar, G. ;Chinnakali, K. ;Balamurugan, R. ;Mohanakrishnan, A. K. ;Fun, Hoong-Kun
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 233 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The non-H atoms of the title molecule, C~13~H~14~N~2~O~3~, are approximately coplanar. The molecules are linked into a two-dimensional network parallel to the __bc__ plane by intermolecular N—H...O, C—H...O and C—H...π interactions.
In the title molecule, C 26 H 24 N 4 O 4 , the ethylcarboxylate plane forms a dihedral angle of 6.23 (7) with the indole ring system. In the crystal structure, pairs of molecules are linked into centrosymmetric dimers by stronginteractions. The dimers are stacked along the b axis.
The title compound, C 14 H 13 NO 5 , exhibits a resonance-assisted hydrogen bond O-HÁ Á ÁO C [2.505 (4) A ˚], which leads to a lengthening of the carbonyl C O bond, a shortening of the C-OH bond and delocalization of the electron density within the dihydropyridine ring.