ETHYL 3-CHLORO-2-ETHOXY-5-FORMYL-6-HYDROXY-4-METHYLBENZOATE
✍ Scribed by Chen, Kau-Ming; Joullié, Madeleine M.
- Book ID
- 121263897
- Publisher
- Taylor and Francis Group
- Year
- 1986
- Tongue
- English
- Weight
- 186 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0030-4948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The molecular structure of (I), with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
In the title compound, C 11 H 11 ClN 2 O, molecules are linked via O-HÁ Á ÁN hydrogen bonds, forming infinite chains running along the c axis with a graph-set motif of C(6). The structure is further stabilized by weakand C-HÁ Á Á interactions.
Hy&o~-5-iodo-2J-dimdimethoxyd-methylbenzoic acid (1) and 5-bromo-4-hydroxy-2,3-dimethoxy-6-methylbenzoic acid (2) are the polysubstituted aromatic carboxylic aciakfoundin calichemicin antibiotics.' The title compounds are synthesized on preparative scale from readily available methyl 4-0-bensylorsel