The crystal structure of the title compound, C 12 H 14 O 5 ΓH 2 O, displays a supramolecular structure via O-HΓ Γ ΓO hydrogen bonds. Nostacking is observed.
Ethyl 3-(2-methyl-1,3-dioxolan-2-yl)-2-(methyldiphenylsilyl)propionate
β Scribed by Barnes, C. L. ;Larson, G. L. ;Santiago, A. ;Steiner, J. R.
- Book ID
- 114505400
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 227 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Geometric parameters of the title compound, C 9 H 10 O 3 , are in the usual ranges. The dioxolane ring adopts an envelope conformation with one of the ring O atoms deviating by 0.477 (4) A Λfrom the plane of the remaining four atoms [C-O-C-C torsion angle = Γ0.6 (3) ]. The molecules are linked by an
Tungsten hexacarbonyl reacts with alkali or tetraalkylammonium halides or pseudohalides MIX (X = halogen or NCS) with elimination of one CO ligand, giving compounds of the type MI[W(CO),X] 121. However, tetraethylammonium azide [31 and W(CO)6 (molar ratio 1 : 15) in diethylene glycol dimethyl ether