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Ethane Pyrolysis in the Presence of Steam

โœ Scribed by Cryder, D. S.; Porter, D. J.


Book ID
126486533
Publisher
American Chemical Society
Year
1937
Weight
941 KB
Volume
29
Category
Article
ISSN
0019-7866

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The pyrolysis of ethane in the presence
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The kinetics of the ethane pyrolysis have been studied at temperatures from 550 to 596'C and with 0 to 620,; of added nitric oxide. The rates of production of various products were studied by gas chromatography; ethylene, hydrogen, methane, nitrogen, water, nitrous oxide and acetonitrile were found

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H2S inhibition of the pyrolysis of ethan
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At 540ยฐC, H,S (0.1 to 5 mm Hg) diminishes the initial rate of pyrolysis of C,H, (50 mm Hg) into C,H, + H, and, even more strongly, the rate of appearance of the traces of nC,H,; on the contrary, the initial rate of formation of the traces of CH, is practically not modified. A mechanism is proposed