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H2S inhibition of the pyrolysis of ethane

โœ Scribed by G. Scacchi; M. Dzierzynski; R. Martin; M. Niclause

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
246 KB
Volume
2
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

At 540ยฐC, H,S (0.1 to 5 mm Hg) diminishes the initial rate of pyrolysis of C,H, (50 mm Hg) into C,H, + H, and, even more strongly, the rate of appearance of the traces of nC,H,;

on the contrary, the initial rate of formation of the traces of CH, is practically not modified.

A mechanism is proposed in order to interpret these experimental facts.

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