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.eta.5-C5Me5TiMe3-B(C6F5)3: A true Ziegler-Natta catalyst for the syndiotactic-specific polymerization of styrene

โœ Scribed by Pellecchia, Claudio; Pappalardo, Daniela; Oliva, Leone; Zambelli, Adolfo


Book ID
127268482
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
251 KB
Volume
117
Category
Article
ISSN
0002-7863

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A combined NMR and electron spin resonan
โœ Alfonso Grassi; Claudio Pellecchia; Leone Oliva; Franco Laschi ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 443 KB

The reaction of (C,(CH,),)Ti(CHZC6H,), with B(C,F,), in chlorobenzene at 25 "C produces a mixture of [(C,(CH,)5 )Ti(CH,C,H,),] + [B(CH2C6H5)(C6F,),] -(1) and Ti(II1) complexes which have been characterized by NMR and electron spin resonance (ESR) spectroscopy, respectively. Spectroscopic data combin