Estimation of the nucleation probability in emulsions
โ Scribed by S. Gibout; M. Strub; J.P. Dumas
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 212 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0017-9310
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โฆ Synopsis
A new method of determination of the nucleation probability of undercooled liquid dispersed within an emulsion is presented. The nucleation probability is a nonlinear function of the temperature depending on two parameters acting very differently. The aim of this paper is to present a method to determine these parameters by an inverse analysis of the heat transfer during the cooling of the emulsion. Information about the precision of the identification is also presented.
๐ SIMILAR VOLUMES
## SYNOPSIS A simple procedure was developed to account for the contribution of freshly nucleated particles to the total polymerization rate during micellar nucleation. It has been shown that the polymerization rate of the freshly nucleated particles cannot be described by a steady-state solution
Newton-Raphson's method plays a fundamental role in the maximum likelihood estimation of the two parameters of the Weibull probability distribution. It is well known that the method depends on the initial point of the iterative process and the iteration does not always converge. In the present art