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SANS study of particle nucleation in emulsion polymerization

✍ Scribed by P.John Feeney; Erik Geissler; Robert G Gilbert; Donald H Napper


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
747 KB
Volume
121
Category
Article
ISSN
0021-9797

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πŸ“œ SIMILAR VOLUMES


The polymerization rate of freshly nucle
✍ M. J. J. Mayer; F. H. A. M. van den Boomen; D. A. Paquet; J. Meuldijk; D. Thoene πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 425 KB πŸ‘ 1 views

## SYNOPSIS A simple procedure was developed to account for the contribution of freshly nucleated particles to the total polymerization rate during micellar nucleation. It has been shown that the polymerization rate of the freshly nucleated particles cannot be described by a steady-state solution

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Based on the coagulative particle nucleation mechanism, a two-step model has been developed for the semi-batch surfactant-free emulsion polymerization of butyl acrylate, or butyl acrylate in the presence of a small amount of acrylic acid. During Stage 1, precursor particles are Ðrst formed by phase