Estimation of effective molecular quadrupole moments
β Scribed by P. T. Eubank
- Publisher
- American Institute of Chemical Engineers
- Year
- 1972
- Tongue
- English
- Weight
- 278 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0001-1541
No coin nor oath required. For personal study only.
β¦ Synopsis
ously published ( 3 ) , and the constants are given in Table 1. Equation (14) fits the isothermal 01 -x -P data within 0.0003 units of relative volatility over a temperature range
π SIMILAR VOLUMES
## Calcuht~onsarc made of the hypcrpolaruabdlty conwburlon to the clcctrlc-f?rld~r~drrnt-InduL~d brrcfrmbcncc which IS used IO mcxure the quadrupolc moments of nondmolar molecules It IS concluded 11~11 h) pcrpol.wzabdlry A%ccs arc small for most, but not A. molecules
The molectilar Zeeman effect has been observed in FC-'CH under high resolution. The data yield the molecular g-value of gr = -0.0077 t 0.0002 and magnetic susceptibilitv anisotropy of xL -x,, = (0.861 z L 0.018) x 10-29 er,aiG%. The combination of these two results gives the molecular quadrupoIe mom
Incomplete total cross sections have been measured for K+ ions scattered by several molecules. By comparing the cross sections at low energy with those measured for the heavier rare gases, it is possible to determine accurate quadrupole moments for the molecules. A novel method for analyzing the exp
Molecular &man effect data for NH, and PH, was reviewed and reanalyzed to obtain molecular quadrupole moments. Since the signs of molecular g-values were not directly measured, molecular quadrupole moments were also calculated using ab initio SCF programs to remove ambiguities in the signs of g-valu