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Esterification of alcohols with acetic acid over ferric oxide

✍ Scribed by J. C. Kuriacose; S. S. Jewur

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
371 KB
Volume
9
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Ferric oxide has been found to promote both the ketonization of acetic acid and its esterification with methyl alcohol, isopropyl alcohol, and benzyl alcohol. The competitive kinetic technique, where the esterification reaction is made to compete with the ketonization of acetic acid, has been used to elucidate the mechanistic model for the ketonization of acetic acid on iron oxide. The ketonization of acetic acid at 375°C is found to be a second‐order reaction which proceeds through a Langmuir‐Hinshelwood mechanism.

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