SINCE the isolation of obacunone C26H3007(I), a bitter principle of Rutaceae, from Phelledendron amurenae, Rupr. by Murayma and Takata' in 1928, it has been investigated by many workers. l-5 Kaku and Ri2 showed that (I) possessed two lactonea (one, c&-unsaturated) and a keto group. Later Kubota and
Establishment of the correlation of obacunone and limonin
β Scribed by T. Kubota; T. Matsuura; T. Tokoroyama; T. Kamikawa; T. Matsumoto
- Publisher
- Elsevier Science
- Year
- 1961
- Tongue
- French
- Weight
- 392 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
ARIGONI, Barton, Corey, Jeger, and collaborators established the complete structure I for limonin. They also proposed the formula II as the plausible and biogenetically attractive one for obacunone. 2 Kubota, Kamikawa, Tokoroyama, and Matsuura proposed the partial structure III on the basis of the degradation reaction of obacunone. 1,3-6 Recently, the partial structure
π SIMILAR VOLUMES
The difference between the structure of coriamyrtin I 1) which was elucidated on the basis of the chemical evidences, and the structure of tutin II which was proposed by the X-2) ray crystallography of a-bromoisotutin and Ct-bromoisotutinone, Mathieson, Tetrahedron Letters 1399 (1963). T. Okuda and