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Establishing coordination numbers for the lanthanides in simple complexes

✍ Scribed by Simon A. Cotton


Book ID
118435352
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
602 KB
Volume
8
Category
Article
ISSN
1631-0748

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## Abstract The novel ytterbium coordination polymer is a two‐dimensional framework in which the central metal ions have four different coordination numbers and form four kinds of coordination polyhedra. The four kinds of coordination polyhedra connect into infinite chains by sharing oxygen atoms.

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The interaction between lanthanide ions Ln"' (Ln = La, Nd, Sm-Dy, Er, Yb) and nitrate ions is investigated by FT-IR spectroscopy in dilute anhydrous MeCN solution. The work is performed for ratios R = [NO;],/[Ln"'], ranging from 0 to 8 and for solutions generally 0 . 0 5 ~ in Ln"', prepared from anh