ESR-Vis/NIR Spectroelectrochemical Study of C70(CF3)2−. and C70(C2F5)2−. Radical Anions
✍ Scribed by Alexey A. Popov; Natalia B. Shustova; Olga V. Boltalina; Steven H. Strauss; Lothar Dunsch
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 715 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1439-4235
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Dimethyl-2,2-bis(trifluoromethyl)azoniaboratacyclo-HC(N 2 )C(=O)OtBu react with 1 to form three-membered rings, which hydrolyze rapidly to form Me 2 NH-CR 1 R 2 -propanes, cyclo-(F 3 C)
## Abstract Reaction of C~70~ with ten equivalents of silver(I) trifluoroacetate at 320–340 °C followed by fractional sublimation at 420–540 °C and HPLC processing led to the isolation of a single abundant isomer of C~70~(CF~3~)~__n__~ for __n__ = 2, 4, 6, and 10, and two abundant isomers of C~70~(