ESR study of the fullerene C60 under axial and shear deformation
โ Scribed by Mikhail V. Motyakin; Natalia G. Spitchina
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 325 KB
- Volume
- 216
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Electron spin resonance spectra of the fullercne Cso were measured at pressures up to 4 GPa (40 kbar) and under shear &formation at ambient temperature. The ESR signal grows in intensity with pressure. The shear deformation transforms Cso molecules to lower-symmetry structures.
๐ SIMILAR VOLUMES
Fluorinated fullerenes have been reported by several groups recently.[', Weight uptake and mass spectrometry studies by Selig et al. ['] have shown that direct fluorination of C,, leads to the formation of C,,F, species with n being an even number (such as C,,F,, , C,,F,, , C,,F4,, etc.) and a negli
It is shown by near-IR that the anion radicals C70 and C2o are formed in vacuum by interaction between the fullerenes C70 and 1-amino-3-propanol (AP) and 1,5-diaminopentane (DAP). The temperature dependence of the ESR spectra for the systems C60-AP, CTo-AP and C7o-DAP were studied. At low temperatur