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E.s.r. study of the alkaline degradation of disaccharides in methyl sulfoxide

✍ Scribed by Paloma Calle; Angela Sanchez; Carlos Sieiro

Book ID
107727167
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
484 KB
Volume
224
Category
Article
ISSN
0008-6215

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The formation of radical intermediates during alkaline, oxidative degradation of saccharides and cw-hydroxycarbonyl compounds has been studied by e.s.r. spectroscopy. Quantum chemical calculation and experiments in alkaline DzO solution showed that the dominant component of the overall spectrum cor