𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ESR study of radicals formed by the reduction of α-diketones C(O)C(O)CF3(R=(CF3)2CF, C6F5, (CF3)3C) with several group I–III metals

✍ Scribed by E. N. Shaposhnikova; S. R. Sterlin; S. P. Solodovnikov; N. N. Bubnov; I. V. Stankevich; A. L. Chistyakov; B. L. Tumanskii

Publisher
Springer
Year
1998
Tongue
English
Weight
380 KB
Volume
47
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

LIF detection of the CF3O radical and ki
LIF detection of the CF3O radical and kinetics of its reactions with CH4 and C2H6
✍ H. Saathoff; R. Zellner 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 469 KB

Fluorescence excitation and dispersed fluorescence spectra of the jz 'E-A 2A, transition of the trifluoromethoxy radical have been measured using laser excitation in the range 336-358 in. The spectra are dominated by the features of the CO stretching and the OCF deformation mode. The LIF technique h

Theoretical Study of the Effects of Phos
Theoretical Study of the Effects of Phosphane Substituents on the Bonding Properties of Acetylene with Ni(PR3)2 (R = H, CH3, F, CF3, C6H5)
✍ Manuel Piacenza; Julia Rakow; Isabella Hyla-Kryspin; Stefan Grimme 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 226 KB 👁 1 views

## Abstract The bond‐formation processes between the d^10^ metal fragments Ni(PR~3~)~2~ (R = H, CH~3~, F, CF~3~, Ph) and acetylene have been studied by density functional theory with the BP86 functional and large TZV(2df,2pd) basis sets. The Ni–acetylene bonds have been analyzed in terms of distort

A comparative study of the ruthenium(VI)
A comparative study of the ruthenium(VI)dioxocarboxylato salts, [PPh4][RuO2(OCOR)Cl2] (R = CH3, CF3, C6H5, C6F5, C5H11), in the oxidation of alcohols
✍ Holger B. Friedrich; Vikash Gokul 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 164 KB

The compounds [PPh 4 ][Ru(O) 2 (OCOR)Cl 2 ] (R = CH 3 1a, CF 3 1b, C 6 H 5 1c, C 6 F 5 1d, C 5 H 11 1e) were prepared and fully characterised. The fluorinated compounds 1b and 1d were obtained in significantly higher yields than their protonated analogues 1a and 1c and compound 1b was found to be a