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ESR study of a paramagnetic titanium methylene complex and of its reactions with olefins

✍ Scribed by Krusic, Paul J.; Tebbe, Fred N.


Book ID
126187758
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
413 KB
Volume
21
Category
Article
ISSN
0020-1669

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## Abstract In the reactions of alkyl‐substituted‐benzenecarboxylic and ‐2‐hydroxybenzenecarboxylic acids (ArCOOH) with alkyl‐substituted phenyl Grignard reagents (RMgX) in the presence of nickel, ketyl radicals ArCO^−^R are formed. The __para__ substituents (H, Me, Et, Isopr and __t__‐Bu) of R i