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ESR studies on the structure of C6F−6 anions

✍ Scribed by Martyn C.R. Symons; Robert C. Selby; Ian G. Smith; Stephen W. Bratt

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
254 KB
Volume
48
Category
Article
ISSN
0009-2614

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✦ Synopsis

W&d soIutkn spectra for C.&g and C#i are compared, and ir is concluded Mat c,5Fz cannot have the planar, u* struttdre previously postulated. Instead, a puckered-ring structure with o and pseudo IT delocalkaiion is postulated.

📜 SIMILAR VOLUMES

Conformational Study by ESR. of Some Alk
Conformational Study by ESR. of Some Alkyl Substituted 6a-Thiathiophthene Radical Anions
✍ Fabian Gerson; Josef Heinzer; Madeleine Stavaux 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 German ⚖ 444 KB

## Abstract ESR. data are reported for the radical anions (II^⊖^ to VI^⊖^) of five alkyl substituted __6a‐thiathiophthenes__. Rates and activation parameters for the inversion of the 3,4‐trimethylene chain in IV^⊖^, V^⊖^ and VI^⊖^ have been obtained by means of an iterative least squares computer p