ESR spectroscopy of some dicyano-, pyrazino- and quinoxalino-1,3,2-dithiazolyl radicals

✍ Scribed by Yuen-Li Chung; Shirley A. Fairhurst; Duncan G. Gillies; Gregor Kraft; Angelika M. L. Krebber; Keith F. Preston; Leslie H. Sutcliffe; Gotthelf Wolmershäuser

• Publisher: John Wiley and Sons
• Year: 1992
• Tongue: English
• Weight: 304 KB
• Volume: 30
• Category: Article
• ISSN: 0749-1581
• DOI: 10.1002/mrc.1260300814

✦ Synopsis

Abstract

Several symmetrical 1,3,2‐dithiazol‐2‐yl radicals have been examined that have in common nitrogen‐containing substituents at the 4‐ and 5‐positions, namely 4,5‐dicyano‐1,3,2‐dithiazol‐2‐yl, [^15^N~2~]‐1,3,2‐dithiazolo [4,5‐b] pyrazin‐2‐yl and 1,3,2‐dithiazoleo [4,5‐b] quinoxalin‐2‐yl. The ESR spectrum of the 4,5‐dicyano radical does not reveal any ^14^N splittings from the cyanide groups; however, the pyrazine and the quinoxaline derivatives do have multi‐lined well resolved spectra arising from substantial hyperfine interactions with these nuclei. The interactions are sufficiently large to be observed in the powder spectra of the latter. The presence of proton hyperfine interactions shows that unpaired‐electron spin density is delocalized over all the rings. It has been found that the radicals attached to pyrazine and quinoxaline can be incorporated into single crystals of naphthalene and phenazine, respectively.