The radical anion of 1,2:9,10-dibenzo[2,2]paracyclophane (3) has been studied by ESR, ENDOR, and TRIPLE resonance spectroscopy under a variety of experimental conditions. The coupling constants of the eight protons in the deck-benzene rings, and of the four inner and four outer protons in the side-b
The Radical Anions of [2.2]Metaparacyclophane-1,9-diene and Some Derivatives: An ESR and ENDOR Study
✍ Scribed by Jürg Bruhin; Urs Buser; Fabian Gerson; Thomas Wellauer
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- German
- Weight
- 648 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
A few preliminary results on lr, 2:, 3:, and 47 have been mentioned in [4].
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Dedicated to Prof. Virgil Boekelheide on the occasion of his 65th birthday (27.XII.84) ## ~ The radical anions of [2.2]paracyclophane-1,9-diene (2) and its 1,10,12,13,15,16-hexadeuterio derivative 2-D6, as well as those of 4,5,7,8-tetramethyl[2.2]paracyclophane-l,9-diene (3) and its 12,13,15,16-t
## Abstract Proton‐hyperfine data are reported for the radical anions generated from azulene (1) and its alkyl derivatives 2–11 in 1,2‐dimethoxyethane both ‘chemically’ with K and electrolytically. The alkyl derivatives are 1,3‐dimethyl‐ (2), 5,7‐dimethyl‐ (3), 1,3,5,7‐tetramethyl‐ (4), 2‐methyl‐ (
The radical cation of bicyclo[2.2.l]hepta-2,5-diene (8,9,10-trinorboma-2,5-diene; 1) in CF,CICFCl, and CF,CCl, matrices and that of bicyclo[2.2.2]octa-2,5-diene (2,3-dihydrobarrelene; 2) in CFC1, and CF,CCl, matrices have been studied by ESR and'ENDOR spectroscopy. For It, the coupling constants of