ESR Spectra of Trifluoromethyl Radical Obtained by Radiolysis and Photolysis in Solid Matrices
โ Scribed by S. R. Allayarov; T. E. Chernysheva; A. I. Mikhailov
- Book ID
- 110336298
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2002
- Tongue
- English
- Weight
- 42 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0018-1439
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๐ SIMILAR VOLUMES
The aim of the study was to bring closer solid state radiation chemistry and ESR spectroscopy by looking for precursors of free radicals which give ESR signals. It has been performed using time-resolved spectrophotometry (pulse radiolysis of the solid state) and diffuse reflection spectrophotometry.
The nlion rJdinl of Icad(ll)Ictraphenylporphyrin W;IS produced by yndlolysisnnd by photolysis of the 1,1.2,2-tetrachloroethanc solutions at 77 K. The hfcc (0 0391 c~') dot to paired electron IS predommantly located m the porphyry ring. "'Pb observed in the CSR spectrum mduates lhat the un-1. introdu