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ESR spectra of the trimethyl—tin and trimethyl—lead radicals

✍ Scribed by J.E. Bennett; J.A. Howard

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
238 KB
Volume
15
Category
Article
ISSN
0009-2614

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✦ Synopsis

The ESR spectra of (CH&Sn-arid (CHa)sPb. hlive been observed. Theg-tensors are anisotropic witngZz 'gfs ( @Y =gxx, and the hypw-inc couplings to "'Sn, 'r9Sn and '07Pb nuclei are extremely large and anisotropic. The results show that there is appreciable spin density in the valence s-orbit& of both radicals, and that the radicals are not plana;, in conirast to the carbon analogue, (CHJ j$..

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