ESR spectra of GeH3 radicals trapped in a matrix of nonmagnetic isotopes of xenon
โ Scribed by Kazutaka Nakamura; Toshiyuki Takayanagi; Makoto Okamoto; Kazuo Shimokoshi; Shin Sato
- Book ID
- 103026511
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 241 KB
- Volume
- 164
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Xenon enriched with nonmagnetic isotopes has been used as a low temperature matrix for the measurement of ESR spectra of GeH3 radicals. Well-resolved proton hypefine structures could be obtained, which were smeared out into a broad singlet in the usual xenon matrix.
๐ SIMILAR VOLUMES
The ESR spectrum of the dihydronitroxide radical. H2N0, isolated in a xenon matrix at iow temperature, hasbcen studied. Analysis of the spectrum leads tT8 = 2.0076 f O\_OOlO,~(H) = 11.8 + 0.2 G, and o(N) = t0.8 t 0.2 G. For the isutopically substituted radical DzNO and I-32 NO, a(D) = I .8 i: 0.2 an