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ESR Proof of the Antiaromaticity of a Cyclopropenyl Radical

✍ Scribed by Dr. Kurt Schreiner; Dipl.-Chem. Wilhelm Ahrens; Prof. Dr. Armin Berndt

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
257 KB
Volume
14
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

ESR spectrum of the cyclopropenyl radica
ESR spectrum of the cyclopropenyl radical
✍ G. Cirelli; F. Graf; Hs.H. GΓΌnthard πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 English βš– 328 KB

The ESR igectkum of a radical produced by phbt6lyticaUy generated I-butoxy radicals anh cyclopropenein solution is reported. A$uments are presented for an assignment of the sp&trum to the cydlopropenyl radical (CH)J un:

The ESR spectrum of a hydrazyl RαΉ„NNH2) r
The ESR spectrum of a hydrazyl RαΉ„NNH2) radical
✍ L. Muszkat πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 253 KB

An ESR study of @radiated sin\_rle c.rystals of cyanoacotyl hydrazide indicates that the free radical formed is the corresponding hydrazyl (NCCH,CONNH,), in which a large fraction of UIC unpaired spin density is located on the a-nitiogcn atom. Stable triaryl substituted hydrazyl free radicals R, -N

ESR study of the tricyclohexylmethyl rad
ESR study of the tricyclohexylmethyl radical
✍ Stefan Luff; John R. Morton; Fabrizia Negri; Mamood Sharifi; Leslie H. Sutcliffe πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 494 KB

The ESR spectrum of the tricyclohexylmethyl radical was obtained from tricyclohexylmethyl chloride and was studied in solution in the range 275-455 K. It has a half-life of about 30 min at room temperature. The complex hyperfioe structure of the radical was analysed with the help of MNDOWHF calculat