ESR of ortho-dimesitoylbenzene-alkali earth metal chelates
โ Scribed by Marina Brustolon; Luigi Pasimeni; Carlo Corvaja
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 231 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The ESR spectra of rlgld glass solutions of bu3dlCclls of ortho-&mesltoylbenzcne -Ion nnd nlknh earth Ion<, were recorded The zero field sphttmg parameter D 1s compared with thzoretlcal values calculated for dlffercnt interIonIc distances The results show that the buadlcal s-pec~es should bz of the contact type wth metal to oxygen dlstancc very close to the sum of the van der Waals rddu of o-cygcn and metrll eons
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## Analysis of the temperature dependence of the electron spin resonance spectra of 4_cyanopyridine-potassium in 1, Z-dimethoxyethaze reveals the presence in solution of two species in thermodynamic equilibrium, The rate of interconversion Between the two species is relatively slow.