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ESR of complexes of 4-cyanopyridine and alkali metals

✍ Scribed by R.F. Adams; N.M. Atherton; A.E. Goggins; Carol M. Goold


Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
235 KB
Volume
1
Category
Article
ISSN
0009-2614

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✦ Synopsis


Analysis of the temperature dependence of the electron spin resonance spectra of 4_cyanopyridine-potassium in 1, Z-dimethoxyethaze reveals the presence in solution of two species in thermodynamic equilibrium, The rate of interconversion

Between the two species is relatively slow.


πŸ“œ SIMILAR VOLUMES


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The preparation and some properties of complexes of 3-and 4-cyanopytiine with the Fe(CN)g-and Co(CN):-groups are described. Visible, IR and NMR spectra indicate a coordination through the pytiine nitrogen. ## Introductbn In this work we describe and discuss the structural properties of complexes

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## Abstract We report herein the kinetic studies on hydrolysis of three cyanopyridines in high‐temperature water. 3‐Cyanopyridine, 4‐cyanopyridine and 2‐cyanopyridine underwent consecutive hydrolysis to the corresponding pyridinecarboxamides and picolinic acids. Further decarboxylation to pyridine