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ESR line width studies of some binary and ternary copper(II) compounds in solution

โœ Scribed by V. G. K. M. Pisipati; N. V. S. Rao; S. Padmaja; Y. Anjaneyulu; R. Prabhakara Rao


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
609 KB
Volume
24
Category
Article
ISSN
0749-1581

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โœฆ Synopsis


The liie widths of the hyperfine components of the ESR spectra of a number of binary and ternary copper(I1) compounds formed with ligands such as acetylacetone, 8-hydroxyquinoline, salicylic acid and diethyldithiocarbamate, in dimethylformamide solution at room temperature, were analysed using the theory developed by Wilson and Kivelson. The results are compared with the experimental hyperfine line widths, and the limitations of the theory are discussed. The agreement between the experimental hyperfine liie widths and the theoretical values is very poor.


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โœ V. G. K. M. Pisipati; N. V. S. Rao; V. Muralikrishna; Premchand ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 827 KB

ESR and optical absorption studies are described for a number of ternary copper(I1) compounds formed with substituted amino acids and different aliphatic polyamines, giving rise to two different immediate environments around copper(II), [3N, OJ and [ZN, 201. The ESR measurements were carried out in