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ESR investigation of the dimerization of some dithiazolidinyl radicals

✍ Scribed by Shirley A. Fairhurst; Neil J. Stewart; Leslie H. Sutcliffe

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 365 KB
Volume: 25
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260250115

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✦ Synopsis

Four types of dithiazolidin-2-yl radical were selected for dimerization measurements in solution. The radicals had different types of substituents and/or different amounts of strain; ESR measurements for a new dithiazolidinyl radical prepared from trans-cyclooctene are presented. Toluene, diethyl ether and chloroform were used as solvents. Radical concentration measurernests incorporated corrections for the variation of the Q of the spectrometer cavity with solvent and temperature. It was found that A H 0 for the dimerization process is dependent only on the radical structure.

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